Jennifer Aniston appeared in the Wednesday, Aug. 27, episode of "Jimmy Kimmel Live!," and revealed that she has tried some of Kimmel's wife's breast milk.

The 45-year-old "Friends" actress and the 46-year-old TV host were talking about his newborn baby daughter, Jane, when the subject of their little chat was sidetracked to breast milk.

"It's like the one milk you don't have to feel guilty about drinking. That dairy is okay. But I had some of Molly's," the Golden Globe-winning actress said, referring to Kimmel's wife Molly McNearney.

"I didn't know if you wanted me to mention that but you did have some," Kimmel responded. "You breastfed my wife."

Aniston corrected him: "I didn't breastfeed her. She breastfed me!"

Then the Brooklyn, New York-born TV host admitted that he has spent a lot of time trying to avoid tasting her wife's breast milk and, in fact, has not tried some of it yet.

"Jimmy, you've got to belly up to the bar, man, you do!" Aniston chided him as the audience laughed.

He joked back: "It's supposed to be for my daughter and what if I like it and I drink all of it? I'm a pig! That's why I have to put my fruit loops in the pancakes."

When asked to describe the flavor of McNearney's milk as compared to cow's milk, Aniston answered, "It's sweet, it's almost coconut-milky. Come on, someone must've tasted breast milk in this audience!"

In July 2013, Kimmel married McNearney, a co-head writer for "Jimmy Kimmel Live," People reported.

And July this year, the couple welcomed their first child, Jane, according to Us Weekly.

In the same interview, Aniston shared that she went to visit Kimmel's little girl, Jane.

"She's a cute little baby. I think she really liked me. She's a mash-up of you and Molly," the actress told Kimmel.

In the same episode of the show, Aniston was reunited with her "Friends" co-stars Courteney Cox and Lisa Kudrow. They all took part in a "Friends" reunion skit, in which they acted out what Kimmel claimed was his own fan fiction, Daily Mail reported.

Watch Kimmel's interview with Aniston below: