Blake Lively has managed to prove once again just how gorgeous she can be. The starlet looks absolutely stunning as she appears in the new ad for Gucci Premiere perfume.

According to E! News, in the shot that appeared on Ryan Reynolds' wife's Instagram page, the blonde beauty looked amazing in a one-shoulder gown as her long hair curled fell down into retro waves giving off the Old Hollywood glam look.

This picture marks the second fragrance campaign Lively has starred in for the Italian brand.

Back in 2012, she reportedly pocketed $4 million for her debut ad with Gucci. An insider revealed, "She has done it smart by not over-endorsing too many brands," adding, "She's gorgeous and her image is a valuable one."

[Check out her latest Gucci campaign ad HERE]

Blake Lively is also currently the face of L'Oreal Paris. When she is not lending her face to high profile brands she is busy working on her lifestyle company and has been filming her first film, "The Age of Adaline" since she married Ryan Reynolds.

Lively stars alongside Harrison Ford in the movie that and it seemed to enjoy her time on the Vancouver set.

She explained, "There's a whimsical suspended reality to it that I love," adding, "And the fashion!"

She confessed, "You don't even need a title card to tell you what year it is - the clothes and the makeup are part of the storytelling."

When it comes to her untitled lifestyle project which is set to launch later this year the former CW star said that there is "nothing like it out there."

Blake Lively has had plenty of time to set up her lifeystyle project once she found time for herself after her television show wrapped. She told Elle, "Having a personal life has been really nice."

She continued, "I'd been on Gossip Girl 10 months a year for six years, shooting 15-hour days, so I hadn't had time to just be since I graduated from high school. It's been nice to kind of settle into my own skin and work on things I really love."